DI Ethanol Amine
Diethanolamine
DEA - DI ETHANOL AMINE is most commonly used as a surfactant, corrosion inhibitor and to remove hydrogen sulfide and carbon dioxide.
Key details
| Generic name | Diethanolamine |
|---|---|
| Standard packing | 210.00 Kg.Liq |
| Supply locations | DI Ethanol Amine manufacturer supplier distributor in Mumbai, Kandla, Kolkata, Vizag, Chennai, India, Fujairah, Dubai UAE, Muscat Oman, Kenya Africa. Get the best quality of DI Ethanol Amine at a competitive price from us. We have ready stock of DI Ethanol Amine in India, UAE Gulf, Oman, Kenya Africa. Contact us for bulk as well as small orders. |
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<span style="font-size:14px;">DEA - DI ETHANOL AMINE is most commonly used as a surfactant in cleaning industries and as a corrosion inhibitor in oil field industries. DI ETHANOL AMINE chemically reacts and remove hydrogen sulfide and carbon dioxide from natural gas due this property <strong>DEA used in oil refineries as a deodourizer to remove hydrogen sulfide from sour gas.</strong></span></p>
<p>
<span style="font-size: 14px; text-align: justify; color: rgb(32, 33, 36); font-family: arial, sans-serif;">Diethanolamine is a white, crystalline (sand-like) solid or a colorless to yellow, syrupy liquid with </span><b style="text-align: justify; color: rgb(32, 33, 36); font-family: arial, sans-serif; font-size: 16px;">a mild Ammonia-like odor</b><span style="font-size: 14px; text-align: justify; color: rgb(32, 33, 36); font-family: arial, sans-serif;">. It is used in specialty textiles, weed killers, detergents, shampoos, paints and metal-working fluids.</span></p>
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PRODUCT NAME </td>
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:</td>
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DI ETHANOL AMINE</td>
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CAS number </td>
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:</td>
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<span class="st">111-42-2</span></td>
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UN number </td>
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2735</td>
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Formula </td>
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:</td>
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(HOCH<strong>2</strong>CH<strong>2</strong>)<strong>2</strong>NH</td>
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Odour </td>
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:</td>
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AMMONIA LIKE</td>
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Solubility in water </td>
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:</td>
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COMPLETE</td>
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Density </td>
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:</td>
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1.09 at 20 <sup>o</sup>C</td>
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Boiling point </td>
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:</td>
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269 <sup>o</sup>C</td>
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Melting point </td>
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:</td>
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28 <sup>o</sup>C</td>
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Viscosity </td>
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</td>
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Flashpoint </td>
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:</td>
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152 <sup>o</sup>C</td>
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Explosive limits </td>
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:</td>
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0.1 mbar at 20 <sup>o</sup>C</td>
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Vapour pressure </td>
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0.1 mbar at 20 <sup>o</sup>C</td>
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Skin absorption/irritation </td>
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YES</td>
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TLV Country NL Year 1995 </td>
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3 ppm 15 mg/m3</td>
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Pollution category 1994 </td>
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:</td>
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D</td>
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<p>
<span style="font-size: 14px; text-align: justify;">DEA produced a dose-dependent decrease (58%) in the antibody-forming cell response to sheep erythrocytes at an 800 mg kg−1 exposure level.</span></p>
<p style="text-align: justify;">
<span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">If RXH is not acid enough to release a proton at alkaline pH, as it is the case with amines, then the reaction has to be carried out in two steps. During the first step the first EO mole is added at acid pH, so that the amine is transformed in ammonium. The reaction produce the mono-, di- and tri-ethanol amines. </span></p>
<p style="text-align: justify;">
<span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">Proton release from ammonium NH</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -2pt;">4</span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT; vertical-align: 3pt;">+ </span>→<span style="font-size: 12pt; font-family: Symbol;"> </span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">NH</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -2pt;">3 </span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">+ H</span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT; vertical-align: 3pt;">+ </span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">(here RX</span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT; vertical-align: 3pt;">- </span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">is NH</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -2pt;">3</span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">) Then, the three condensation reactions: </span></p>
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<span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">NH</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -3pt;">3 </span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">+ </span><span style="font-size: 12pt; font-family: TimesNewRomanPS; font-weight: 700;">EO </span>→<span style="font-size: 12pt; font-family: Symbol;"> </span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">NH</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -3pt;">2</span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">CH</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -3pt;">2</span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">CH</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -3pt;">2</span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">OH (mono-ethanol amine MEA) <br />
NH</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -3pt;">2</span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">CH</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -3pt;">2</span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">CH</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -3pt;">2</span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">OH + </span><span style="font-size: 12pt; font-family: TimesNewRomanPS; font-weight: 700;">EO </span>→<span style="font-size: 12pt; font-family: Symbol;"> </span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">NH(CH</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -3pt;">2</span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">CH</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -3pt;">2</span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">OH)</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -3pt;">2 </span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">(di-ethanol amine DEA) <br />
NH-(CH</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -3pt;">2</span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">CH</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -3pt;">2</span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">OH)</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -3pt;">2 </span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">+ </span><span style="font-size: 12pt; font-family: TimesNewRomanPS; font-weight: 700;">EO </span>→<span style="font-size: 12pt; font-family: Symbol;"> </span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">N(CH</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -3pt;">2</span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">CH</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -3pt;">2</span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">OH)</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -3pt;">3 </span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">(tri-ethanol amine TEA) </span></p>
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<span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">With an alkyl amine, first the alkyl ammoniumion is formed and it is deprotonated: </span></p>
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<span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">RNH</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -3pt;">3</span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT; vertical-align: 3pt;">+ </span><span style="text-align: justify;">→</span><span style="font-size: 12pt; font-family: Symbol;"> </span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">RNH</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -3pt;">2 </span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">+ H</span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT; vertical-align: 3pt;">+ </span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">(here RX</span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT; vertical-align: 3pt;">- </span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">is RNH</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -2pt;">2</span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">)<br />
RNH</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -3pt;">2 </span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">+ </span><span style="font-size: 12pt; font-family: TimesNewRomanPS; font-weight: 700;">EO </span><span style="text-align: justify;">→</span><span style="font-size: 12pt; font-family: Symbol;"> </span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">RNH-CH</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -3pt;">2</span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">CH</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -3pt;">2</span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">OH (mono-ethanol alkyl amine) <br />
RNH-CH</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -3pt;">2</span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">CH</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -3pt;">2</span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">OH + </span><span style="font-size: 12pt; font-family: TimesNewRomanPS; font-weight: 700;">EO </span><span style="text-align: justify;">→</span><span style="font-size: 12pt; font-family: Symbol;"> </span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">RN(CH</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -3pt;">2</span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">CH</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -3pt;">2</span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">OH)</span><span style="font-size: 10pt; font-family: TimesNewRomanPSMT; vertical-align: -3pt;">2 </span><span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">(di-ethanol alkyl amine) </span></p>
<p style="text-align: justify;">
<span style="font-size: 12pt; font-family: TimesNewRomanPSMT;">Once the ethanol amine is attained, the EO polycondensation is carried out at alkaline pH as previously. In many instance the first ethoxylation is stopped when the monoethanol alkyl amine is formed in order to avoid the polycondensation in more than one chain. </span></p>
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