CESIUM ACETATE 99

Lab Chemical-60

CESIUM ACETATE 99

CESIUM ACETATE 99

Key details

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Application

<p style="text-align: justify;">
<span style="text-align: justify; color: rgb(32, 33, 34); font-family: sans-serif; font-size: 14px;">APPLICATION: used in organic synthesis. One example is in the </span><a class="mw-redirect" href="https://en.wikipedia.org/wiki/Perkin_synthesis&quot; style="background-image: none; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial; text-align: justify; text-decoration-line: none; color: rgb(6, 69, 173); font-family: sans-serif; font-size: 14px;" title="Perkin synthesis">Perkin synthesis</a><span style="text-align: justify; color: rgb(32, 33, 34); font-family: sans-serif; font-size: 14px;">: the formation of </span><a href="https://en.wikipedia.org/wiki/Saturated_and_unsaturated_compounds&quot; style="background-image: none; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial; text-align: justify; text-decoration-line: none; color: rgb(6, 69, 173); font-family: sans-serif; font-size: 14px;" title="Saturated and unsaturated compounds">unsaturated</a><span style="text-align: justify; color: rgb(32, 33, 34); font-family: sans-serif; font-size: 14px;"> </span><a href="https://en.wikipedia.org/wiki/Cinnamic_acid&quot; style="background-image: none; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial; text-align: justify; text-decoration-line: none; color: rgb(6, 69, 173); font-family: sans-serif; font-size: 14px;" title="Cinnamic acid">cinnamic-type acids</a><span style="text-align: justify; color: rgb(32, 33, 34); font-family: sans-serif; font-size: 14px;"> by the condensation of</span><span style="color: rgb(32, 33, 36); font-family: arial, sans-serif; font-size: 16px;"> Cesium acetate is used </span><b style="color: rgb(32, 33, 36); font-family: arial, sans-serif; font-size: 16px;">in organic synthesis especially in Perkin reaction to prepare unsaturated cinnamic-type acids</b><span style="color: rgb(32, 33, 36); font-family: arial, sans-serif; font-size: 16px;">. It is used in petroleum drilling fluids as an alternative to cesium formate.</span><span style="color: rgb(32, 33, 34); font-family: sans-serif; font-size: 14px;"> aromatic </span><a href="https://en.wikipedia.org/wiki/Aldehyde&quot; style="background-image: none; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial; text-decoration-line: none; color: rgb(6, 69, 173); font-family: sans-serif; font-size: 14px;" title="Aldehyde">aldehydes</a><span style="color: rgb(32, 33, 34); font-family: sans-serif; font-size: 14px;"> with </span><a href="https://en.wikipedia.org/wiki/Fatty_acid&quot; style="background-image: none; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial; text-decoration-line: none; color: rgb(6, 69, 173); font-family: sans-serif; font-size: 14px;" title="Fatty acid">fatty acids</a><span style="color: rgb(32, 33, 34); font-family: sans-serif; font-size: 14px;">. </span></p>

Using Procedure

<p style="text-align: justify;">
<span style="font-size:14px;"><span style="color: rgb(28, 29, 30); font-family: "Open Sans", sans-serif;"> commercially available. Cesium acetate has been prepared by stirring a solution of cesium carbonate in dry methanol, followed by the addition of acetic acid. Methanol was removed after 1 h under reduced pressure to yield the desired product as a white solid</span></span></p>

Note

<p style="text-align: justify;">
<span style="font-size:14px;"><span style="color: rgb(51, 51, 51); font-family: Arial;">This is not so much due its molar solubility (only 5.26 M) but more due to its high molar weight. Caesium acetate is occasionally used instead of caesium formate in petroleum drilling fluids</span></span></p>

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