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<strong><em><span style="font-family:georgia,serif;"><span style="font-size:14px;">Salicylaldehyde is converted to chelating ligands by condensation with amines. With ethylenediamine, it condenses to give the ligand salen. Hydroxylamine gives salicylaldoxime. Condensation with diethyl malonate gives 3-carbethoxycoumarin (a derivative of coumarin) by an aldol condensation.</span></span></em></strong></p>
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<strong><em><span style="font-family:georgia,serif;"><span style="font-size:14px;">Salicylaldehyde is prepared by heating phenol and chloroform together in the presence of potassium hydroxide and sodium hydroxide. This reaction is called the Relmer-Tiemann reaction. The correct option is Option C, Reimer-Tiemann reaction.</span></span></em></strong></div>
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<strong><em><span style="font-family:georgia,serif;"><span style="font-size:14px;">Salicylic acid can be synthesized from salicylaldehyde using KMnO4 without oxidising the hydroxy group (−OH). The hydroxy group that attached to the benzene isn't oxidized, because the C atom that bonded with the hydroxy has already use 2 electrons for sigma bonding and 1 electron for pi bonding.</span></span></em></strong></p>
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