TETRA BUTYL AMMONIUM HYDROXIDE 10% AQUEOUS SOLUTION

Lab Chemical-60

TETRA BUTYL AMMONIUM HYDROXIDE 10% AQUEOUS SOLUTION

TETRA BUTYL AMMONIUM HYDROXIDE 10% AQUEOUS SOLUTION

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Application

<div aria-level="3" role="heading">
<strong><em><span style="font-family:georgia,serif;"><span style="font-size:14px;">Tetrabutylammonium hydroxide solution (TBAOH) may be used in the following studies:</span></span></em></strong></div>
<div>
<ul>
<li>
<strong><em><span style="font-family:georgia,serif;"><span style="font-size:14px;">For the dissolution of 10wt% cellulose under room temperature conditions.</span></span></em></strong></li>
<li>
<strong><em><span style="font-family:georgia,serif;"><span style="font-size:14px;">As a catalyst during the synthesis of 1,2,4-oxadiazoles.</span></span></em></strong></li>
<li>
<strong><em><span style="font-family:georgia,serif;"><span style="font-size:14px;">Preparation of TBAOH salts of fatty acids.</span></span></em></strong></li>
</ul>
</div>

Using Procedure

<p>
<span style="color:#000;"><strong><em><span style="font-family:georgia,serif;"><span style="font-size:14px;">Solutions of Bu4NOH are usually prepared in situ from butylammonium halides, Bu4NX, for example by reacting them with </span></span></em></strong></span><strong><em><span style="font-family:georgia,serif;"><span style="font-size:14px;"><a href="https://en.wikipedia.org/wiki/Silver_oxide&quot; title="Silver oxide"><span style="color:#000;">silver oxide</span></a><span style="color:#000;"> or using an </span><a href="https://en.wikipedia.org/wiki/Ion_exchange_resin&quot; title="Ion exchange resin"><span style="color:#000;">ion exchange resin</span></a><span style="color:#000;">. Attempts to isolate Bu4NOH induces </span><a href="https://en.wikipedia.org/wiki/Hofmann_elimination&quot; title="Hofmann elimination"><span style="color:#000;">Hofmann elimination</span></a><span style="color:#000;">, leading to Bu3N and </span><a href="https://en.wikipedia.org/wiki/1-butene&quot; title="1-butene"><span style="color:#000;">1-butene</span></a></span></span></em></strong><span style="color:#000;"><strong><em><span style="font-family:georgia,serif;"><span style="font-size:14px;">. Solutions of Bu4NOH are typically contaminated with Bu3N for this reason</span></span></em></strong></span></p>

Note

<p>
<span style="color:#000;"><strong><em><span style="font-family:georgia,serif;"><span style="font-size:14px;"><span style="background-color:#fff;">Tetrabutylammonium hydroxide is the </span></span></span></em></strong></span><strong><em><span style="font-family:georgia,serif;"><span style="font-size:14px;"><a href="https://en.wikipedia.org/wiki/Chemical_compound&quot; title="Chemical compound"><span style="color:#000;"><span style="background-color:#fff;">chemical compound</span></span></a><span style="color:#000;"><span style="background-color:#fff;"> with the formula (C4H9)4NOH, abbreviated Bu4NOH with the acronym TBAOH or TBAH. This species is employed as a solution in water or </span></span><a href="https://en.wikipedia.org/wiki/Alcohol&quot; title="Alcohol"><span style="color:#000;"><span style="background-color:#fff;">alcohols</span></span></a><span style="color:#000;"><span style="background-color:#fff;">. It is a common base in </span></span><a href="https://en.wikipedia.org/wiki/Organic_chemistry&quot; title="Organic chemistry"><span style="color:#000;"><span style="background-color:#fff;">organic chemistry</span></span></a><span style="color:#000;"><span style="background-color:#fff;">. Relative to more conventional inorganic bases, such as </span></span><a href="https://en.wikipedia.org/wiki/Potassium_hydroxide&quot; title="Potassium hydroxide"><span style="color:#000;"><span style="background-color:#fff;">KOH</span></span></a><span style="color:#000;"><span style="background-color:#fff;"> and </span></span><a href="https://en.wikipedia.org/wiki/NaOH&quot; title="NaOH"><span style="color:#000;"><span style="background-color:#fff;">NaOH</span></span></a></span></span></em></strong><span style="color:#000;"><strong><em><span style="font-family:georgia,serif;"><span style="font-size:14px;"><span style="background-color:#fff;">, Bu4NOH is more soluble in organic solvents.</span></span></span></em></strong></span></p>

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